防冻剂喷洒装置改造方案的研究

通过对现有防冻剂喷洒装置缺点的分析和研究,确定了执行机构和控制系统的改造方案。通过对喷洒装置进行改造,实现了喷洒装置自动化控制。     

冷喷涂固态颗粒沉积中颗粒间结合形成机制研究进展

就目前主流的冷喷涂颗粒结合形成机理进行了系统总结和评述,为冷喷涂沉积体性能的调控和后续研究提供借鉴。分别就经典的颗粒界面绝热剪切失稳结合机理,颗粒界面应力波释放诱导材料射流形成结合机理,以及高速碰撞诱导颗粒表面氧化膜破碎、新鲜金属接触结合机理的基本概念、原理、特点进行了概括总结。通过大量系统文献的调研,指出现有理论目前存在的相悖和不足之处,并简要分析了现有颗粒间结合形成理论对冷喷涂沉积体质量调控方面的指导意义。最后基于现有研究的不足,对冷喷涂颗粒界面结合机制方面的研究进行了展望。     

铝合金拐臂盒件铸造工艺优化

铝合金拐臂盒铸件轴孔处容易产生缩松缺陷,对此进行了原因分析和工艺改进。依据铸造凝固理论结合实际生产经验,采用不同热导率的金属材料的冷铁及增加工艺补贴等方法,对铸造工艺进行优化。优化后经过X光无损检测及机加工验证,成功解决了轴孔处缩松的铸造缺陷。     

Deposition and characterization of earth abundant CuZnS ternary thin films by vacuum spray pyrolysis and fabrication of p-CZS/n-AZO heterojunction solar cells

We report fabrication of solar cell device <ITO/AZO/i-ZnO/CZS/Al> with Copper Zinc Sulfide (CZS) thin films as absorber layer. CZS thin films prepared using chemical spray pyrolysis technique at a pressure of 10⁻³ mbar at different substrate temperatures. Structural, morphological, optical, compositional and electrical properties of as prepared films are investigated. Structural analysis shows crystalline nature with mixed phase containing CuS-ZnS binary composite. Atomic Force Microscopy analysis shows the average particle size of 88 nm. Value of work function obtained from ultraviolet photoelectron spectroscopy is 4.58 eV. The band gap of the as-prepared films varies from 1.62 to 2.06 eV. Hall effect measurement proves the p-type nature for all the deposited films. Samples deposited at 350°C shows carrier concentration of 10²¹ cm⁻³ and electrical conductivity of 526 S cm⁻¹. Solar cell device structure of <ITO/AZO/i-ZnO/CZS/Al> has been fabricated using the CZS sample deposited at 350°C. The cell parameters obtained are V_oc = 0.505 V, I_sc = 4.97 mA/cm², FF = 64.28% and η = 1.6 ± 0.05%.     

双层分流燃烧室内空间利用和喷雾分布的研究

应用可视化方法测试了不同喷油参数条件下3种双层分流燃烧室内的燃油喷雾扩散过程,探讨燃烧室的碰撞台、燃烧空间容积比例、燃烧空间形状等结构特征以及喷油压力和喷油正时等喷油参数对燃烧室内空间利用和燃油喷雾分布的影响.结果表明:提高喷油压力和提前喷油正时均增大了燃油喷雾的分布范围,提前喷油正时使燃油喷雾更早地进入了顶隙空间,降低了燃烧室结构对燃油喷雾分布的影响,但燃烧室的空间利用率下降;降低碰撞台位置和增大上层燃烧空间容积有利于燃烧室顶层空间的利用;剥离面可以促进下层燃烧空间内燃油喷雾的扩散;上层燃烧空间采用凸圆弧底面使燃烧室顶层区域在较早喷油正时时获得了较好的利用.     

汽油/柴油掺混燃油两段喷射喷雾特性试验研究

基于定容燃烧弹与超高速数码相机搭建的LED-Mie散射喷雾试验台,研究了不同参数对柴油、汽油质量占比20%的柴汽混合油(记为G20)单段与两段喷射主喷液相喷雾特性的影响。结果表明,单段喷射喷雾贯穿距与喷雾锥角随喷射压力的增大而增大,G20喷雾贯穿距略小于柴油喷雾贯穿距,G20喷雾锥角略大于柴油喷雾锥角。将环境温度由300K升高到850K,喷雾贯穿距变小且喷雾很快达到稳定。冷态环境下(300K),两段喷射主喷喷雾贯穿距起始阶段与单段喷射喷雾贯穿距基本一致,但随着喷雾发展200μs左右后,两段喷射主喷喷雾贯穿距变得略小于单段喷射喷雾贯穿距。两段喷射主喷喷雾锥角略大于单段喷射喷雾锥角,预主喷间隔时间对喷雾锥角影响较小。     

Effect of iron content on the wear behavior and adhesion strength of TiC–Fe nanocomposite coatings on low carbon steel produced by air plasma spray

In this study, the effect of Fe content on the abrasion behavior of TiC–Fe nanocomposite coatings applied on the CK45 steel substrate by air plasma spray method was investigated. For this purpose, milled TiC powder was prepared at 1, 2, 3 and 4 h milled TiC powder for 4 h was selected as the suitable sample. In the next step, a suitable sample mixture with different iron powder concentrations of 5, 10, 15, 20 and 25% was prepared by mechanical milling. The granulated mixture was applied to the substrate using air plasma spray technique. Microstructural and phase analyzes were performed using X-ray diffraction (XRD) and Scanning Electron Microscopy (SEM). According to the results of Williamson-Hall calculations, the TiC crystallites' size decreased by 49 nm–29 nm, and network strain reached 0.16% by increasing milling time from 1 h to 4 h. Studies have shown that the coatings contain titanium carbide, iron oxide, and titanium oxide, with the number of phases formed depending on the amount of iron in the chemical composition. Investigation of the tribological properties of the coating layer showed that with increased iron content in the coating, the wear resistance of the samples is reduced. Hardness tests on coatings indicate that adding iron to nanocomposite from 5 to 25% reduces hardness from 1025 to 699 Hv. It can be argued that a slight increase in the adhesion strength of the coating to the substrate is due to increased wettability because of the formation of molten iron in the coating.     

边坡支护施工技术在肯尼亚某大坝工程中的应用

肯尼亚斯瓦克大坝项目位于肯尼亚东南部,是通过修建一座混凝土面板堆石坝蓄水,开发河水资源用以供水、发电和灌溉多功能一体化的工程。苏州中材建设有限公司负责施工的溢洪道土石方开挖,涉及溢洪道两边边坡支护技术。文章详细介绍了该工程的边坡支护施工过程,提出了其施工质量保证措施和支护工程质量通病处理工艺及措施。     

Fatigue strength and microstructure evaluation of Al 7050 alloy wires recycled by spray forming,extrusion and rotary swaging

Recycled high-strength aluminum alloys have limited use as structural materials due to poor mechanical properties. Spray forming remelting followed by hot extrusion is a promising route for reprocessing 7xxx alloys. The 7050 alloy machining chips were spray formed, hot extruded, rotary swaged and heat-treated in order to improve mechanical properties. Microstructures, tensile properties and fatigue strength results for a 2.7 mm-diameter recycled wire are presented. Secondary phases and precipitates were investigated by XRD, SEM, EBSD, TEM and DSC. As-swaged and heat-treated (solution and aging) conditions were evaluated. Mechanical properties of both conditions outperformed AA7050 aerospace specification. Substantial grain refinement resulted from the extensive plastic deformation imposed by rotary swaging. Refined micrometric and sub-micrometric Al grains, as well as coarse and fine intermetallic precipitates were observed. Subsequent solution treatment resulted in a homogeneous, recrystallized and equiaxed microstructure with grain size of 9 μm. Nanoscale GP(I) zones and η′ phase precipitates formed after aging at 120 °C, imparting higher tensile (586 MPa) and fatigue (198 MPa) strengths.     

Grain size effect on microwave dielectric properties of Na2WO4 ceramics prepared by cold sintering process

In this work, cold sintering was adopted to prepare Na₂WO₄ ceramics with different grain sizes ranging from 0.632 μm to 17.825 μm. Their microstructures, complex impedance, and microwave dielectric properties were studied in-depth. It was found that samples with relative densities higher than 92% can be successfully synthesized by cold sintering process at a low temperature of 240 °C. However, their electrical properties have strong dependence on the grain size. Specifically, the resistance of grain boundaries decreases dramatically with the increase of grain sizes, while the quality factor has a positive correlation with the grain sizes of Na₂WO₄ ceramics. Excellent microwave dielectric properties, including permittivity = 5.80, Q × f = 22,000 GHz, and TCF = −70 ppm/°C, are obtained for Na₂WO₄ ceramics with a grain size of 4.477 μm prepared by cold sintering process.